Hey again @Marydoyouknow,
Thank you for using our platform so actively!
As our member Pampel_Muse outlined well on this thread you started: Ex-Muslim asylum seeker, you are able to apply for asylum while transiting in Munich airport.
The following thread may also be interesting for you to understand the process in general:
In the International transit zone in Frankfurt airport - who should I ask for help to start my asylum application?
Also, here is some more information on applying for asylum at the airport by the BAMF: http://www.bamf.de/EN/Fluechtlingsschutz/Sonderverfahren/FlughafenVerfahren/flughafenverfahren-node.html
I hope this helps. Let me know if you have any more questions :-)
All the best,